196398
Furan-3-methanol
99%
Synonym(s):
3-(Hydroxymethyl)furan
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About This Item
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Quality Level
Assay
99%
form
liquid
refractive index
n20/D 1.484 (lit.)
bp
79-80 °C/17 mmHg (lit.)
density
1.139 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
OCc1ccoc1
InChI
1S/C5H6O2/c6-3-5-1-2-7-4-5/h1-2,4,6H,3H2
InChI key
STJIISDMSMJQQK-UHFFFAOYSA-N
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General description
Furan-3-methanol on oxidation with pyridinium chlorochromate yields furan-3-carboxaldehyde.
Application
Furan-3-methanol was used in the synthesis of substituted δ2-butenolides and 1-benzyl-3-(furan-3-ylmethyl)-3-methylpyrrolidin-2-one.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
100.4 °F - closed cup
Flash Point(C)
38 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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3-Alkylfurans as useful synthetic equivalents for substituted δ2-butenolides.
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Stannylation/destannylation. Preparation of. alpha.-alkoxy organolithium reagents and synthesis of dendrolasin via a carbinyl carbanion equivalent.
Journal of the American Chemical Society, 100(5), 1481-1487 (1978)
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