161756
Bromomethyl methyl ether
technical grade, 90%
Synonym(s):
1-Bromomethyl methyl ether, Bromomethoxymethane, Methoxymethyl bromide
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About This Item
Linear Formula:
BrCH2OCH3
CAS Number:
Molecular Weight:
124.96
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical grade
Quality Level
Assay
90%
form
liquid
refractive index
n20/D 1.456 (lit.)
bp
87 °C (lit.)
density
1.531 g/mL at 25 °C (lit.)
functional group
bromo
ether
storage temp.
2-8°C
SMILES string
COCBr
InChI
1S/C2H5BrO/c1-4-2-3/h2H2,1H3
InChI key
JAMFGQBENKSWOF-UHFFFAOYSA-N
Related Categories
Application
Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
80.6 °F - closed cup
Flash Point(C)
27 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Nuclear analogs of β-lactam antibiotics. XVI. Aldol condensations of N-protected 4-tritylthio-2-azetidinones.
Martel A, et al.
Canadian Journal of Chemistry, 61(3), 613-618 (1983)
Enantioselective synthesis of the C (18)-C (35) segment of immunosuppressant FK-506 using efficient new methodology.
Corey EJ and Huang H-C.
Tetrahedron Letters, 30(39), 5235-5238 (1989)
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 161756-25G | 4061838746610 |
| 161756-5G | 4061837005909 |
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