15450
N,N′-Dimethylurea
(sym.), ≥99% (from N)
Synonym(s):
DMU, 1,3-Dimethylurea
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About This Item
Linear Formula:
(CH3NH)2CO
CAS Number:
Molecular Weight:
88.11
Beilstein:
1740672
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥99% (from N)
form
solid
reaction suitability
reagent type: ligand
reaction type: C-H Activation
bp
268-270 °C (lit.)
mp
101-104 °C (lit.)
103-107 °C
SMILES string
CNC(=O)NC
InChI
1S/C3H8N2O/c1-4-3(6)5-2/h1-2H3,(H2,4,5,6)
InChI key
MGJKQDOBUOMPEZ-UHFFFAOYSA-N
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Application
N,N′-Dimethylurea can be used:
- As a starting material to synthesize N,N′-dimethyl-6-amino uracil.
- In combination with β-cyclodextrin derivatives, to form low melting mixtures (LMMs), which can be used as solvents for hydroformylation and Tsuji-Trost reactions.
- To synthesize N,N′-disubstituted-4-aryl-3,4-dihydropyrimidinones via Biginelli condensation under solvent-free conditions.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
314.6 °F - closed cup
Flash Point(C)
157 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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