759198
Di(1-adamantyl)-1-piperidinylphenylphosphine
95%
Synonym(s):
2-(Di-1-adamantylphosphino)phenylpiperidine
About This Item
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Assay
95%
form
powder
reaction suitability
reagent type: ligand
mp
225-230 °C
functional group
phosphine
SMILES string
[H][C@]1(C[C@](C2)([H])C3)C[C@]3([H])C[C@]2([P@@](C4=CC=CC=C4N5CCCCC5)[C@@]67C[C@@](C8)([H])C[C@@](C[C@@]8([H])C7)([H])C6)C1
InChI
1S/C31H44NP/c1-4-8-32(9-5-1)28-6-2-3-7-29(28)33(30-16-22-10-23(17-30)12-24(11-22)18-30)31-19-25-13-26(20-31)15-27(14-25)21-31/h2-3,6-7,22-27H,1,4-5,8-21H2/t22-,23+,24-,25-,26+,27-,30-,31-
InChI key
FPQYIRBFZLNVLL-OSESXBJYSA-N
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Articles
DalPhos is air-stable and contains the bulky di(1-adamantyl)phosphino [P(1-Ad)2] fragment. These ligands are useful in Pd-catalyzed C-N and C-C bond formation. Both Me-DalPhos and Mor-DalPhos allow for Pd-catalyzed ammonia, hydrazine and acetone cross-coupling with good functional group tolerance
Related Content
The main focus of the Stradiotto group has centered on the development and application of novel electronically rich, sterically encumbered P,N-based ancillary ligands for use in late metal catalysis, including Pd and Au chemistry.
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