- Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides.
Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides.
Organic & biomolecular chemistry (2005-04-29)
Yoshihiko Yamamoto, Tomoaki Saigoku, Hisao Nishiyama, Takashige Ohgai, Kenji Itoh
PMID15858662
ZUSAMMENFASSUNG
In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides.
MATERIALIEN