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Merck

442794

Supelco

tert-Amylmethylether

analytical standard

Synonym(e):

1,1-Dimethylpropylmethylether, Methyl-2-methyl-2-butylether, Methyl-tert.-pentylether, TAME

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About This Item

Lineare Formel:
C2H5C(CH3)2OCH3
CAS-Nummer:
Molekulargewicht:
102.17
Beilstein:
1731452
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12000000
PubChem Substanz-ID:

Qualität

analytical standard

Analysenzertifikat (CofA)

current certificate can be downloaded

Verpackung

ampule of 1000 mg

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Brechungsindex

n20/D 1.389 (lit.)
n20/D 1.3896

bp

85-86 °C (lit.)

Dichte

0.76-0.78 g/mL at 25 °C (lit.)

Anwendung(en)

environmental

Format

neat

Lagertemp.

2-30°C

SMILES String

CCC(C)(C)OC

InChI

1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3

InChIKey

HVZJRWJGKQPSFL-UHFFFAOYSA-N

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Allgemeine Beschreibung

tert-Amyl methyl ether (TAME) is a fuel oxygenate which is utilized as an additive in gasoline to enhance the octane rating and to improve combustion.

Anwendung

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TAME has been used as a reference standard for the determination of the analyte in Catalonian groundwater and soil samples by purge-and-trap gas chromatography/mass spectrometry (P&T-GC/MS) and in aqueous solutions by solid-phase microextraction (SPME) combined with GC-MS. It may be used as a reference standard for the identification of the analyte in gasoline-contaminated groundwater by GC combined with various detectors/quantification methods such as photoionization detector (PID), flame ionization detector (FID), or MS.

Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3

Zielorgane

Central nervous system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

19.4 °F - closed cup

Flammpunkt (°C)

-7 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Choose from one of the most recent versions:

Analysenzertifikate (COA)

Lot/Batch Number

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If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

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Die Dokumentenbibliothek aufrufen

Trace analysis of ethanol, MTBE, and related oxygenate compounds in water using solid-phase microextraction and gas chromatography/mass spectrometry
Cassada DA, et al.
Analytical Chemistry, 72(19), 4654-44658 (2000)
Evaluation of standard methods for the analysis of methyl tert-butyl ether and related oxygenates in gasoline-contaminated groundwater
Halden RU, et al.
Environmental Science & Technology, 35(7), 1469 -11474 (2001)
Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography -mass spectrometry
Rosell M, et al.
Journal of Chromatography A, 1132(1-2), 28 -238 (2006)
Single-walled carbon nanotubes as an effective adsorbent in solid-phase microextraction of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether from human urine
Rastkari N, et al.
Journal of Chromatography. B, Biomedical Applications, 877(14-15), 1568-11574 (2009)
Determination of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether in human urine by HS-SPME gas chromatography/mass spectrometry
Scibetta L, et al.
Analytica Chimica Acta, 581(1), 53 -562 (2007)

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