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Merck

07313

Supelco

Demeton-S-methylsulfon

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Empirische Formel (Hill-System):
C6H15O5PS2
CAS-Nummer:
Molekulargewicht:
262.28
Beilstein:
1712536
MDL-Nummer:
UNSPSC-Code:
41116107
NACRES:
NA.24

Qualität

certified reference material
TraceCERT®

Qualitätsniveau

Produktlinie

TraceCERT®

Haltbarkeit

limited shelf life, expiry date on the label

Hersteller/Markenname

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Format

neat

Lagertemp.

2-8°C

SMILES String

CCS(=O)(=O)CCSP(=O)(OC)OC

InChI

1S/C6H15O5PS2/c1-4-14(8,9)6-5-13-12(7,10-2)11-3/h4-6H2,1-3H3

InChIKey

PZIRJMYRYORVIT-UHFFFAOYSA-N

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Allgemeine Beschreibung

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma aldrich.com

Demeton-S-methyl sulfone is an insecticide that belongs to the class of organophosphorus compounds, the major group of pest controllers used in agricultural production.

As per Regulation (EC) No 1107/2009, demeton-S-methyl-sulfon is not approved for use in European Union. Maximum residue levels (MRLs) have been set according to Regulation (EU) No 889/2012 for oxydemeton-methyl as a sum of oxydemeton-methyl and Demeton-S-methylsulfone expressed as oxydemeton-methyl for various products of plant and animal origin from 0.01 to 0.05 mg/kg.

Anwendung

It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques. Demeton-S-methyl sulfone CRM may also find its use as described below:
  • Validation of a method to monitor 11 organophosphorus residues in samples of banana, papaya, and bell pepper using QuEChERS extraction and high performance liquid chromatography with tandem mass spectrometry (HPLC-MS/MS)(1)
  • Simultaneous determination of four pesticides, aldicarb, demeton-S-methyl, fenamiphos, and methiocarb and their metabolites in grape juices using solid-phase extraction and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Quantification and confirmation of 16 priority pesticides in baby foods and their comparison using HPLC-MS/MS and UPLC-MS/MS coupled with tandem quadrupole mass spectrometry
  • Development of reversed phase liquid chromatography-electrospray ionization-tandem mass spectrometry method for the determination of 52 pesticides in tobacco
  • Validation of two variations of the QuEChERS method for the determination of 120 pesticides and metabolites in cereal-based infant foods by LC-MS/MS with electrospray interface (ESI)

Empfohlene Produkte

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Rechtliche Hinweise

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Skull and crossbonesEnvironment

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Chronic 2

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Analysenzertifikate (COA)

Lot/Batch Number

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Yolanda Picó et al.
Analytical and bioanalytical chemistry, 389(6), 1805-1814 (2007-07-21)
Various studies have been drawn toward the beneficial properties of fruit juices because they have several components, such as phenols, vitamins, and flavonoids, with antioxidant effects. However, fruit juices can also contain residues of pesticides used as standard pest control
Bernhard Mayer-Helm
Journal of chromatography. A, 1216(51), 8953-8959 (2009-11-21)
A method using reversed phase liquid chromatography-electrospray ionization-tandem mass spectrometry was developed for the determination of 52 pesticides in tobacco. The influence of mobile phase additives was investigated to improve sensitivity and accuracy of the method and to reduce matrix

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