375810

Periodsäure

ACS reagent, 99%

• Empirische Formel (Hill-System): H₅IO₆
• CAS-Nummer: 10450-60-9
• Molekulargewicht: 227.94
• EG-Nummer: 233-937-0
• MDL-Nummer: MFCD00011344
• UNSPSC-Code: 12352106
• PubChem Substanz-ID: 329755660
• NACRES: NA.21

Eigenschaften

• Qualität: ACS reagent
• Assay: 99%; 99.0-101.0% (ACS specification)
• Form: powder or crystals
• Eignung der Reaktion: reaction type: C-H Activation; reagent type: catalyst; reagent type: oxidant
• Verunreinigungen: ≤0.01% insolubles; ≤0.01% other halogens
• Glührückstand: ≤0.01%
• mp (Schmelzpunkt): 122 °C (lit.)
• Löslichkeit: water: soluble
• Anionenspuren: sulfate (SO₄^2-): ≤0.01%
• Kationenspuren: Fe: ≤0.003%; heavy metals: ≤0.005%
• Anwendung(en): histology
• SMILES String: OI(O)(O)(O)(O)=O
• InChI: 1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
• InChIKey: TWLXDPFBEPBAQB-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Periodic acid is an inorganic acid commonly used as an oxidizing agent. Periodic acid oxidation is one of the steps in the periodate-resorcinol assay, used in the determination of sialic acid. Periodic acid reacts with 1,2 glycol linkage of carbohydrates to form aldehydes which can be stained by Schiff′s reagent. Therefore periodic-acid-Schiff′s reagent (PAS) is used in histochemistry to determine carbohydrates in tissue sections.

Anwendung

Periodic acid may be used in the following reactions:

• Oxidation of alcohols to ketones and aldehydes.
• Oxidation hydroxylamine derivatives.
• Oxidation of arenes to quinones.
• Deprotection of the dithio- and oxathio-derivatives.
• Oxidative degradation of epoxidized natural rubber (ENR).
• Oxidation of urazoles and bis-urazoles to triazolinediones.
• Oxidative cleavage of glucosazone.

Sicherheitshinweise

• Piktogramme: GHS03,GHS08,GHS05,GHS09
• Signalwort: Danger
• H-Sätze: H271,H314,H372,H410
• P-Sätze: P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral
• Zielorgane: Thyroid
• Lagerklassenschlüssel: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable