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221716

Sigma-Aldrich

Ammoniumoxalat Monohydrat

ACS reagent, ≥99%

Synonym(e):

Oxalsäure Diammoniumsalz

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About This Item

Lineare Formel:
(NH4)2C2O4 · H2O
CAS-Nummer:
Molekulargewicht:
142.11
Beilstein:
3759830
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NB.24

Qualität

ACS reagent

Dampfdruck

<0.1 hPa ( 20 °C)

Assay

≥99%
99.0-101.0% (ACS specification)

Form

crystalline powder
crystals or granules

Verunreinigungen

≤0.005% insolubles

Glührückstand

≤0.02%

pH-Wert

6-7 (25 °C, 14.2 g/L)

mp (Schmelzpunkt)

133 °C (dec.) (lit.)

Anionenspuren

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.002%

Kationenspuren

Fe: ≤2 ppm
heavy metals: ≤5 ppm (by ICP)

SMILES String

OC(C(O)=O)=O.N.O.N

InChI

1S/C2H2O4.2H3N.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);2*1H3;1H2

InChIKey

MSMNVXKYCPHLLN-UHFFFAOYSA-N

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Allgemeine Beschreibung

Ammonium oxalate monohydrate is a diammonium salt of oxalic acid. Its refined crystal structure has been investigated by three-dimensional diffraction studies. Influence of bivalent [Mn(II), Co(II), Ni(II)] and trivalent cations [Fe(III), Cr(III)] impurities on the growth rates of ammonium oxalate monohydrate crystals has been described. Its space group and unit cell parameters have been analyzed by neutron diffraction studies. Its IR spectra have been compared with that of isolated coal-solubilizing agent (CSA).

Anwendung

Ammonium oxalate monohydrate may be used in the preparation of tetramethylammonium oxalate.

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Piktogramme

Exclamation mark

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Irrit. 2

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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A convenient method for preparation of quaternary ammonium salts.
Markowitz M.
The Journal of Organic Chemistry, 22(8), 983-984 (1957)
Yeonho Kim et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(46), 10510-10518 (2020-03-27)
In this work, environmentally friendly photocatalysts with attractive catalytic properties are reported that have been prepared by introducing SnO2 quantum dots (QDs) directly onto ZnSe(N2 H4 )0.5 substrates to induce advantageous charge separation. The SnO2 /ZnSe(N2 H4 )0.5 nanocomposites could
Sina Matavos-Aramyan et al.
Free radical biology & medicine, 106, 158-167 (2017-02-19)
Three novel modified advanced oxidation process systems including ascorbic acid-, pro-oxidants- and ascorbic acid-pro-oxidants-modified Fenton system were utilized to study the disinfection efficiency on Cryptosporidium-contaminated drinking water samples. Different concentrations of divalent and trivalent iron ions, hydrogen peroxide, ascorbic acid
M S Cohen et al.
Applied and environmental microbiology, 56(11), 3285-3291 (1990-11-01)
Low-ranked coals were dissolved by using cell extracts derived from liquid cultures of Trametes versicolor. The coal-solubilizing agent (CSA) was separated from the broth components by a multistep isolation procedure including reverse-phase high-pressure liquid chromatography, size exclusion chromatography, ethanol fractionation

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