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Merck

87997

Supelco

Tetrapentylammoniumbromid

suitable for ion pair chromatography, LiChropur, ≥99.0% (AT)

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About This Item

Lineare Formel:
[CH3(CH2)4]4N(Br)
CAS-Nummer:
Molekulargewicht:
378.47
Beilstein:
3658171
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12000000
PubChem Substanz-ID:
NACRES:
NB.21

Beschreibung

cationic

Qualitätsniveau

Assay

≥99.0% (AT)

Form

powder

Qualität

LiChropur

Methode(n)

ion pair chromatography: suitable

mp (Schmelzpunkt)

100-101 °C (lit.)

λ

10 % in methanol

UV-Absorption

λ: 240 nm Amax: 0.04
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

Eignung

corresponds to standard for filter test

SMILES String

[Br-].CCCCC[N+](CCCCC)(CCCCC)CCCCC

InChI

1S/C20H44N.BrH/c1-5-9-13-17-21(18-14-10-6-2,19-15-11-7-3)20-16-12-8-4;/h5-20H2,1-4H3;1H/q+1;/p-1

InChIKey

SPALIFXDWQTXKS-UHFFFAOYSA-M

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Allgemeine Beschreibung

Tetrapentylammonium bromide is a quaternary ammonium bromide, with pentyl chains and a bromide counter-ion, which is widely used as an ion-pair reagent in analytical applications.

Anwendung

Tetrapentylammonium bromide may be used as a standard, to examine the effects of annealing membranes formed by mixture-casting ”Nafion” mainly based on the selectivity, ion-exchange capacity, and mass transport in the membranes. It may also be used as an ion pair reagent in the analysis of antioxidant phenolic compounds in wines, juices using two-dimensional liquid chromatography and sulfonated lignins in agrochemical formulations using one-, two-dimensional liquid chromatography techniques.

Sonstige Hinweise

Additiv bei der Ionenpaar-Chromatographie; Induziert längere Retentionszeiten als das Tetrabutyl-Homologe

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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Comprehensive two-dimensional liquid chromatography in the analysis of antioxidant phenolic compounds in wines and juices
Kivilompolo M, et al.
Analytical and Bioanalytical Chemistry, 391(1), 373-380 (2008)
K. Sagara et al.
Journal of Chromatography A, 328, 289-289 (1985)
A.T. Hunter
Journal of Chromatography A, 319, 319-319 (1985)
Roger C Lo et al.
Bioanalysis, 4(6), 693-701 (2012-03-29)
Different markers have been used to label DNA for sample detection in gel electrophoresis. Intercalating dyes, (e.g., YOYO) have been widely used to label DNA for sample detection, because they do not require the use of radioisotopes, covalent attachment or
Nishant Chetwani et al.
Analytical chemistry, 83(8), 3017-3023 (2011-03-23)
The novel effects resulting from the entrainment of low mobility ions during alternating current (ac) electrospray ionization are examined through mass spectrometry and voltage/current measurements. Curious phenomena such as pH modulation at high frequencies (>150 kHz) of an applied ac

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