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86899

Supelco

Tetrabutylammoniumphosphat monobasisch -Lösung

suitable for ion pair chromatography, LiChropur, concentrate, ampule

Synonym(e):

Tetrabutylammonium-dihydrogenphosphat -Lösung

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About This Item

Lineare Formel:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS-Nummer:
Molekulargewicht:
339.45
Beilstein:
5196532
MDL-Nummer:
UNSPSC-Code:
12000000
PubChem Substanz-ID:
NACRES:
NB.21

Beschreibung

cationic

Qualitätsniveau

Form

liquid

Qualität

LiChropur
ampule

Verpackung

ampule of 25 mL

Methode(n)

ion pair chromatography: suitable

λ

in concentrate

UV-Absorption

λ: 210 nm Amax: 0.05
λ: 220 nm Amax: 0.04
λ: 300 nm Amax: 0.02
λ: 500 nm Amax: 0.02

Eignung

corresponds to standard for RP gradient test
corresponds to standard for filter test

Lagertemp.

2-8°C

SMILES String

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

InChIKey

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

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Allgemeine Beschreibung

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.
Tetrabutylammonium dihydrogen phosphate is a quaternary ammonium salt mainly used as electrolyte.

Anwendung

Tetrabutylammonium dihydrogen phosphate has been used as ion-pairing reagent in mobile phase for ion-pair HPLC analysis of 5′-mononucleotides from baby formulae. It may also have been used in mobile phase for HPLC analysis of blood samples to determine acetaminophen.

Sonstige Hinweise

Ionenpaarreagenz für die Umkehrphasenchromatographie

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Lagerklassenschlüssel

10 - Combustible liquids

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Die Dokumentenbibliothek aufrufen

The analysis of 5'-mononucleotides in infant formulae by HPLC.
Perrin, Christian, et al.
Food Chemistry, 74.2, 245-253 (2001)
K Makino et al.
Journal of chromatography, 400, 271-277 (1987-07-29)
The separation of large oligodeoxyribonucleotides, synthesized chemically and subsequently deblocked, was carried out by reversed-phase ion-pair chromatography (RP-IPC) with a linear gradient of acetonitrile concentration. It was found that tetrabutylammonium phosphate is suitable as an ion-pairing reagent and produces a
In situ gelling and mucoadhesive liquid suppository containing acetaminophen: enhanced bioavailability.
Choi, Han-Gon, Yu-Kyoung Oh, and Chong-Kook Kim.
International Journal of Pharmaceutics, 165.1, 23-32 (1998)
C.F. Harrington et al.
Journal of Liquid Chromatography and Related Technologies, 20, 1773-1773 (1997)
W.E. Ladner et al.
The Journal of Organic Chemistry, 50, 1076-1076 (1985)

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