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Supelco

Ethylacrylat

analytical standard

Synonym(e):

Acrylsäureethylester

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About This Item

Lineare Formel:
CH2=CHCOOC2H5
CAS-Nummer:
140-88-5
Molekulargewicht:
100.12
Beilstein:
773866
EG-Nummer:
205-438-8
MDL-Nummer:
MFCD00009188
UNSPSC-Code:
85151701
PubChem Substanz-ID:
329766922
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

100

Dampfdichte

3.5 (vs air)

Dampfdruck

31 mmHg ( 20 °C)

Assay

≥99.5% (GC)

Selbstzündungstemp.

721 °F

Haltbarkeit

limited shelf life, expiry date on the label

Enthält

~0.002% hydroquinone monomethyl ether as stabilizer

Expl.-Gr.

12.1 %

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Brechungsindex

n20/D 1.406 (lit.)
n20/D 1.406

bp

99 °C (lit.)

mp (Schmelzpunkt)

−71 °C (lit.)

Dichte

0.921 g/mL at 20 °C
0.918 g/mL at 25 °C (lit.)

Anwendung(en)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care
petroleum

Format

neat

SMILES String

CCOC(=O)C=C

InChI

1S/C5H8O2/c1-3-5(6)7-4-2/h3H,1,4H2,2H3

InChIKey

JIGUQPWFLRLWPJ-UHFFFAOYSA-N

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Allgemeine Beschreibung

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Find all available reference materials for compounds listed in 10/2011 here

Anwendung

Ethyl acrylate can undergo anionic polymerization upon initiation by tetrabutylammonium azide in the presence of alkylaluminum bisphenoxides in toluene to yield azide-end poly(ethyl acrylate) (PEA).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Piktogramme

FlameSkull and crossbones
GHS02,GHS06

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

48.2 °F - closed cup

Flammpunkt (°C)

9 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Analysenzertifikate (COA)

Lot/Batch Number
BCCF7422
BCCC8184
BCBZ8590
BCBW9179
BCBW2546

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Methacrylsäure (stabilised with hydroquinone monomethyl ether) for synthesis

Sigma-Aldrich

8.00578

Methacrylsäure

Methylmethacrylat 99%, stabilized

Sigma-Aldrich

W400201

Methylmethacrylat

Butylacrylat ≥99%, contains 10-60 ppm monomethyl ether hydroquinone as inhibitor

Sigma-Aldrich

234923

Butylacrylat

2-(Diethylamino)ethylacrylat 95%, contains 25 ppm monomethyl ether hydroquinone as inhibitor

Sigma-Aldrich

408972

2-(Diethylamino)ethylacrylat

Methylacrylat (stabilised with hydroquinone monomethyl ether) for synthesis

Sigma-Aldrich

8.00841

Methylacrylat

Farnesol analytical standard, stabilized, mixture of isomers

Supelco

43348

Farnesol

Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate
Kataoka Y, et al.
Polym. Chem. (2017)
Junliang Wu et al.
Journal of the American Chemical Society, 131(39), 13888-13889 (2009-09-15)
The direct cross-coupling of quinoline-N-oxides with olefin derivatives has been realized using palladium acetate as the catalyst in the absence of external ligand and oxidant to give the corresponding 2-alkenylated quinolines and 1-alkenylated isoquinolines chemo- and regioselectively in 27-95% yield.
M Shahjahan Kabir et al.
The Journal of organic chemistry, 77(1), 300-310 (2011-11-15)
The stereospecific synthesis of aryloxy and amino substituted E- and Z-ethyl-3-acrylates is of interest because of their potential in the polymer industry and in medicinal chemistry. During work on a copper-catalyzed cross-coupling reaction of ethyl (E)- and (Z)-3-iodoacrylates with phenols
Aaron Mark Drucker et al.
Dermatitis : contact, atopic, occupational, drug, 22(2), 98-101 (2011-04-21)
Acrylates are present in a wide variety of products and cause occupational and non-occupational allergic contact dermatitis. There is no clear guidance from the literature as to which allergens should be used for patch-test screening for acrylates. To characterize patients
Anna E V Hagström et al.
Biotechnology and bioengineering, 102(3), 693-699 (2008-09-30)
An OH-functional polyester has been acrylated via transesterification of ethyl acrylate, catalyzed by Candida antarctica lipase B (CalB) in two different preparations: Novozym 435 and immobilized on Accurel MP1000. The batch process resulted in incomplete acrylation as well as severe
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