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Merck

379263

Sigma-Aldrich

2-Methyl-2-buten

technical grade, 90%

Synonym(e):

β-Isoamylen, Amylen

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About This Item

Lineare Formel:
CH3CH=C(CH3)2
CAS-Nummer:
Molekulargewicht:
70.13
Beilstein:
1361353
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

technical grade

Qualitätsniveau

Dampfdichte

2.4 (vs air)

Dampfdruck

25.7 psi ( 55 °C)
7.95 psi ( 20 °C)

Assay

90%

Form

liquid

Expl.-Gr.

8.7 %

Brechungsindex

n20/D 1.385 (lit.)

bp

35-38 °C (lit.)

mp (Schmelzpunkt)

−134 °C (lit.)

Dichte

0.662 g/mL at 25 °C (lit.)

SMILES String

C\C=C(\C)C

InChI

1S/C5H10/c1-4-5(2)3/h4H,1-3H3

InChIKey

BKOOMYPCSUNDGP-UHFFFAOYSA-N

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Allgemeine Beschreibung

2-Methyl-2-butene (β-Isoamylene, Amylene) is a trisubstituted olefin. It acts as guest and forms stable solid host-guest complexes with self-assembled benzophenone bis-urea macrocycles. The effect of active chlorine formulations on photodecomposition of 2-methyl-2-butene has been studied. Its reaction with ozone in gas-phase has been reported to afford carbonym derivatives.

Anwendung

2-Methyl-2-butene may be employed as precursor for peroxyacetyl nitrate for the calibration purposes.

Empfohlene Produkte

Brass hose adapter Z146811 or brass body mini gas regulator Z513539 is recommended.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3

Zielorgane

Central nervous system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

-4.0 °F

Flammpunkt (°C)

-20 °C

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves


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Gas-phase reaction of ozone with 2-methyl-2-butene: Dicarbonyl formation from Criegee biradicals.
Grosjean D.
Environmental Science & Technology, 24(9), 1428-1432 (1990)
Michael F Geer et al.
The Journal of organic chemistry, 78(11), 5568-5578 (2013-05-16)
This manuscript investigates how incorporation of benzophenone, a well-known triplet sensitizer, within a bis-urea macrocycle, which self-assembles into a columnar host, influences its photophysical properties and affects the reactivity of bound guest molecules. We further report the generation of a
Yunseok Im et al.
The Science of the total environment, 409(13), 2652-2661 (2011-04-29)
Active chlorine comprising hypochlorite (OCl⁻), hypochlorous acid (HOCl) and chlorine (Cl₂) is the active constituent in bleach formulations for a variety of industrial and consumer applications. However, the strong oxidative reactivity of active chlorine can cause adverse effects on both
Charles K Westbrook et al.
The journal of physical chemistry. A, 119(28), 7462-7480 (2015-03-31)
Two experimental studies have been carried out on the oxidation of 2-methyl-2-butene, one measuring ignition delay times behind reflected shock waves in a stainless steel shock tube, and the other measuring fuel, intermediate, and product species mole fractions in a
Masataka Ikeda et al.
Scientific reports, 5, 15881-15881 (2015-10-31)
The heart has two major modalities of hypertrophy in response to hemodynamic loads: concentric and eccentric hypertrophy caused by pressure and volume overload (VO), respectively. However, the molecular mechanism of eccentric hypertrophy remains poorly understood. Here we demonstrate that the

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