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Merck

31658

Supelco

Rimsulfuron

PESTANAL®, analytical standard

Synonym(e):

1-(4,6-Dimethoxy-2-pyrimidinyl)-3-[3-(ethylsulfonyl)-2-pyridylsulfonyl]-harnstoff

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About This Item

Empirische Formel (Hill-System):
C14H17N5O7S2
CAS-Nummer:
Molekulargewicht:
431.44
Beilstein:
7501778
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Produktlinie

PESTANAL®

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

agriculture
environmental

Format

neat

SMILES String

CCS(=O)(=O)c1cccnc1S(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2

InChI

1S/C14H17N5O7S2/c1-4-27(21,22)9-6-5-7-15-12(9)28(23,24)19-14(20)18-13-16-10(25-2)8-11(17-13)26-3/h5-8H,4H2,1-3H3,(H2,16,17,18,19,20)

InChIKey

MEFOUWRMVYJCQC-UHFFFAOYSA-N

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Allgemeine Beschreibung

Rimsulfuron is a sulfonylurea herbicide primarily used to control a wide variety of perennial and annual grasses and some broadleaf weeds. The mode of action of rimsulfuron involves inhibition of acetolactate synthase (ALS), a key enzyme in the biosynthetic pathway of branched-chain amino acids.

Anwendung

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Rimsulfuron may be used as a reference standard for the determination of the analyte:
  • In honey samples using a method based on an on-column liquid-liquid extraction (OCLLE) using diatomaceous earth as inert solid support and liquid chromatography (LC) coupled to mass spectrometry (MS) operating in tandem mode (MS/MS).

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Analysenzertifikate (COA)

Lot/Batch Number

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Die Dokumentenbibliothek aufrufen

Development and validation of a multi-residue method for pesticide determination in honey using on-column liquid- liquid extraction and liquid chromatography- tandem mass spectrometry.
Pirard C, et al.
Journal of Chromatography A, 1152(1-2), 116-123 (2007)
Basis of selectivity of the herbicide rimsulfuron in maize.
Koeppe MK, et al.
Pesticide Biochemistry and Physiology, 66(3), 170- 181 (2000)
Paola Ganugi et al.
Plant science : an international journal of experimental plant biology, 303, 110727-110727 (2021-01-26)
Herbicide application is a common procedure in agriculture, whose potentially adverse effects are assessed mainly with respect to weeds or in terms of residues and environmental impact. However, recent evidence has highlighted possible effects of pesticide treatments on plant metabolism
Shuo Wang et al.
Bulletin of environmental contamination and toxicology, 105(4), 602-606 (2020-09-27)
A method for simultaneous quantitation of rimsulfuron, quizalofop-P-ethyl and quizalofop-P in potato plant, soil and potato tuber samples was established. The mean recoveries of rimsulfuron, quizalofop-P-ethyl and quizalofop-P in different matrices spiked with them were 81.4%-101.1%, 76.1%-99.0% and 77.4%-106.4% with
Amit Paporisch et al.
Pesticide biochemistry and physiology, 138, 22-28 (2017-05-01)
Three sweet corn genotypes, two inbred lines (IBER001 and IBER002) and their hybrid (ER00X), differ in their phenotypic responses to several P450-metabolized herbicides, used in sweet corn, namely, foramsulfuron, iodosulfuron, rimsulfuron and tembotrione. Foramsulfuron is a sulfonylurea herbicide commonly formulated

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