06061

Allyl-phenylsulfon

purum, ≥98.0% (GC)

• Synonym(e): (2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone
• Lineare Formel: C₆H₅SO₂CH₂CH=CH₂
• CAS-Nummer: 16212-05-8
• Molekulargewicht: 182.24
• Beilstein: 1863561
• EG-Nummer: 240-338-8
• MDL-Nummer: MFCD00014739
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 329748204
• NACRES: NA.22

Eigenschaften

• Qualität: purum
• Qualitätsniveau: 200
• Assay: ≥98.0% (GC)
• Form: liquid
• Brechungsindex: n20/D 1.548 (lit.); n20/D 1.548
• bp: 110-113 °C/0.5 mmHg (lit.)
• Dichte: 1.189 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: C=CCS(=O)(=O)c1ccccc1
• InChI: 1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
• InChIKey: KYPIULIVYSQNNT-UHFFFAOYSA-N

Beschreibung

Anwendung

Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles

Possible usages of allyl phenyl sulfone:

• It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
• It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
• It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter