M5852
2-Mercaptopyridin
ReagentPlus®, 99%
Synonym(e):
2-Pyridinthiol, 2-Pyridylmercaptan
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Alle Fotos(1)
About This Item
Empirische Formel (Hill-System):
C5H5NS
CAS-Nummer:
Molekulargewicht:
111.16
Beilstein:
105787
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Produktlinie
ReagentPlus®
Assay
99%
mp (Schmelzpunkt)
127-130 °C (lit.)
Lagertemp.
2-8°C
SMILES String
Sc1ccccn1
InChI
1S/C5H5NS/c7-5-3-1-2-4-6-5/h1-4H,(H,6,7)
InChIKey
WHMDPDGBKYUEMW-UHFFFAOYSA-N
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Verwandte Kategorien
Allgemeine Beschreibung
2-Mercaptopyridine is an organosulfur compound that contains more than one hetero atom. It is commonly used as a nucleophile in various organic synthesis reactions and plays important role in coordination chemistry as a versatile ligand due to its π-acidic nature.
Anwendung
Wird als Ligand in Metallkomplexen verwendet.
Rechtliche Hinweise
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Journal of the American Chemical Society, 141(31), 12305-12311 (2019-07-10)
The potential advantages of using arylboronic esters as boron sources in C-H borylation are discussed. The concept is showcased using commercially available 2-mercaptopyridine as a metal-free catalyst for the transfer borylation of heteroarenes using arylboronates as borylation agents. The catalysis
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 3, 741-741 (1992)
Partha Halder et al.
Inorganic chemistry, 50(3), 708-710 (2010-12-25)
Iron(II) tris(2-pyridylthio)methanido (1) containing an Fe-C bond, obtained from the reaction of tris(2-pyridylthio)methane (HL(1)) and iron(II) triflate, reacts with protic acid to generate iron(II) bis(2-pyridylthio)carbene (1a). The carbene complex is converted to an iron(II) complex (2) of the 1-[bis(2-pyridylthio)methyl]pyridine-2-thione ligand
Alexey V Chuchuryukin et al.
Inorganic chemistry, 45(5), 2045-2054 (2006-02-28)
A silver-free route has been employed for the synthesis of a number of Pd and Pt complexes supported by an NCN "pincer" ligand (NCN = [2,6-(Me2NCH2)2C6H3]-) via halide abstraction. This was achieved by the use of o-, m-, and p-hydroxypyridines
H I Abdulla et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(13), 2659-2671 (2002-01-05)
The infrared spectra of 2-hydroxypyridine (2-OHP), 2-thiopyridine (2-SHP), and 2-aminopyridine (2-NH2P) have been recorded in the solid, liquid and vapor phases in the region 4000-200 cm(-1). To support the work, deuterated forms of these compounds in the functional groups XH
Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..
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