798835

[Ru(phd)₃](PF₆)₂

• Synonym(e): Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• Empirische Formel (Hill-System): C₃₆H₁₈F₁₂N₆O₆P₂Ru
• CAS-Nummer: 184023-77-6
• Molekulargewicht: 1021.56
• UNSPSC-Code: 12352202
• PubChem Substanz-ID: 329768673
• NACRES: NA.22

Eigenschaften

• Form: powder
• Eignung der Reaktion: core: ruthenium; reagent type: catalyst
• SMILES String: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• InChIKey: LGAOGZFZNIEFHF-UHFFFAOYSA-N

Beschreibung

Anwendung

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Rechtliche Hinweise

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable