681482

2-(Allyldimethylsilyl)pyridin

90%

• Synonym(e): Allyldimethyl-(2-pyridyl)-silan
• Lineare Formel: (CH₂CHCH₂)Si(CH₃)₂(C₅H₄N)
• CAS-Nummer: 118722-54-6
• Molekulargewicht: 177.32
• MDL-Nummer: MFCD09265157
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24885637
• NACRES: NA.22

Eigenschaften

• Assay: 90%
• Brechungsindex: n20/D 1.5046
• Dichte: 0.913 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: C[Si](C)(CC=C)c1ccccn1
• InChI: 1S/C10H15NSi/c1-4-9-12(2,3)10-7-5-6-8-11-10/h4-8H,1,9H2,2-3H3
• InChIKey: WIRIPVDRZYVTCG-UHFFFAOYSA-N

Beschreibung

Anwendung

2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 160.0 °F - closed cup
• Flammpunkt (°C): 71.1 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter