561673

1-Naphthylmagnesiumbromid -Lösung

0.25 M slurry in THF

• Empirische Formel (Hill-System): C₁₀H₇BrMg
• CAS-Nummer: 703-55-9
• Molekulargewicht: 231.37
• MDL-Nummer: MFCD00015768
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24879961
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 0.25 M slurry in THF
• bp: 65 °C
• Dichte: 0.908 g/mL at 25 °C
• SMILES String: Br[Mg]c1cccc2ccccc12
• InChI: 1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1
• InChIKey: PZIIGUMPOSVMSD-UHFFFAOYSA-M

Beschreibung

Anwendung

1-Naphthylmagnesium bromide can be used:

• To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
• As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.

Rechtliche Hinweise

Product of Rieke^® Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H314,H335,H351
• P-Sätze: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup