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Sigma-Aldrich

Tris[N,N-bis(trimethylsilyl)amid]samarium(III)

98%

Synonym(e):

1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium

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About This Item

Lineare Formel:
Sm(N(Si(CH3)3)2)3
CAS-Nummer:
35789-01-6
Molekulargewicht:
631.51
MDL-Nummer:
MFCD03427097
UNSPSC-Code:
12352300
PubChem Substanz-ID:
24879000
NACRES:
NA.22

Qualitätsniveau

100

Assay

98%

Form

solid

Eignung der Reaktion

core: samarium
reagent type: catalyst

mp (Schmelzpunkt)

93-106 °C (lit.)

SMILES String

C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/3C6H18NSi2.Sm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

InChIKey

MUFPZLRACJKLCI-UHFFFAOYSA-N

Verwandte Kategorien

Anwendung

Reactant for synthesis of:
  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

Piktogramme

FlameCorrosion
GHS02,GHS05

Signalwort

Danger

Gefahreneinstufungen

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

Zusätzliche Gefahrenhinweise

EUH014

Lagerklassenschlüssel

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 3

Flammpunkt (°F)

36.0 °F - closed cup

Flammpunkt (°C)

2.2 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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Hung-Che Chou et al.
Colloids and surfaces. B, Biointerfaces, 73(2), 244-249 (2009-06-24)
This paper utilizes a silver electrode quartz crystal microbalance (QCM) mass sensor to detect the physiology of cells. This study also investigates the plasma surface modification of silver electrode QCMs through deposition of hexamethyldisilazane (HMDSZ) films as a protection film.
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Tatsuya Nitabaru et al.
Journal of the American Chemical Society, 131(38), 13860-13869 (2009-09-10)
Full details of an anti-selective catalytic asymmetric nitroaldol reaction promoted by a heterobimetallic catalyst comprised of Nd(5)O(O(i)Pr)(13), an amide-based ligand, and NaHMDS (sodium hexamethyldisilazide) are described. A systematic synthesis and evaluation of amide-based ligands led to the identification of optimum
Nondestructively creating nanojunctions by combined-dynamic-mode dip-pen nanolithography.
Guanxia Shen et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 10(13), 2226-2229 (2009-07-16)
Juliana Tsz Yan Lee et al.
Scanning, 34(1), 12-25 (2012-04-26)
Common dehydration methods of cells on biomaterials for scanning electron microscopy (SEM) include air drying, hexamethyldisilazane (HMDS) or tetramethysilane (TMS) treatment and critical point drying (CPD). On the other side, freeze-drying has been widely employed in dehydrating biological samples and
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