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2,5-Thiophendicarboxaldehyd
99%
Synonym(e):
2,5-Diformylthiophene, 2,5-Thienodicarboxaldehyde, 2,5-Thiophenedial, Thiophene-2,5-dialdehyde
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About This Item
Empfohlene Produkte
Qualitätsniveau
Assay
99%
mp (Schmelzpunkt)
115-117 °C (lit.)
Funktionelle Gruppe
aldehyde
SMILES String
[H]C(=O)c1ccc(s1)C([H])=O
InChI
1S/C6H4O2S/c7-3-5-1-2-6(4-8)9-5/h1-4H
InChIKey
OTMRXENQDSQACG-UHFFFAOYSA-N
Allgemeine Beschreibung
2,5-Thiophenedicarboxaldehyde can be prepared from 2,5-bis(chloromethyl)thiophene by the application of Kröhnke′s method.
Anwendung
2,5-Thiophenedicarboxaldehyde may be employed in the following studies:
- Asymmetric synthesis of bis-homoallylic alcohols.
- Synthesis of new symmetrical arylene bisimide derivatives.
- As dialdehyde monomer in the synthesis of silicon-containing poly(p-phenylenevinylene)-related copolymers having uniform p-conjugated segment regulated by organosilicon units.
- Synthesis of 2,5-bis[2-(5-N-isopropylamidino)benzimidazoyl]thiophene hydrochloride.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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The Preparation of 2, 5-Thiophenedicarboxaldehyde.
Bulletin of the Chemical Society of Japan, 37(8), 1197-1200 (1964)
The journal of physical chemistry. C, Nanomaterials and interfaces, 118(24), 13070-13086 (2014-06-27)
New symmetrical arylene bisimide derivatives formed by using electron-donating-electron-accepting systems were synthesized. They consist of a phthalic diimide or naphthalenediimide core and imine linkages and are end-capped with thiophene, bithiophene, and (ethylenedioxy)thiophene units. Moreover, polymers were obtained from a new
The Journal of organic chemistry, 64(3), 721-725 (2001-10-25)
Asymmetric reduction of 2,6-diacylpyridines with B-chlorodiisopinocampheylborane provides the corresponding C(2)-symmetric diols in very high de and ee. Asymmetric allylboration of 2,6-pyridinedicarboxaldehyde and 2,5-thiophenedicarboxaldehyde provides the corresponding bis-homoallylic alcohols in very high de and ee. These optically pure diols were converted
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