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Merck

373761

Sigma-Aldrich

2,2,2-Trifluorethylmethacrylat

contains 50-200 ppm MEHQ as inhibitor, 99%

Synonym(e):

2,2,2-Trifluoroethyl 2-methylprop-2-enoate

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise


About This Item

Lineare Formel:
H2C=C(CH3)CO2CH2CF3
CAS-Nummer:
Molekulargewicht:
168.11
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12162002
PubChem Substanz-ID:
NACRES:
NA.23

Qualitätsniveau

Assay

99%

Form

liquid

Enthält

50-200 ppm MEHQ as inhibitor

Brechungsindex

n20/D 1.361 (lit.)

bp

59 °C/100 mmHg (lit.)

Dichte

1.181 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

CC(=C)C(=O)OCC(F)(F)F

InChI

1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3

InChIKey

QTKPMCIBUROOGY-UHFFFAOYSA-N

Allgemeine Beschreibung

2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant.

Anwendung

TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.

Piktogramme

FlameSkull and crossbones

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Flam. Liq. 2

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

62.6 °F - closed cup

Flammpunkt (°C)

17 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Yoshinori Kadoma
Dental materials journal, 29(5), 602-608 (2010-09-10)
The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA) and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC) in order to improve the properties of fluorinated powder-liquid
Arda Yurtsever et al.
Electrophoresis, 30(4), 589-598 (2009-01-22)
A new, fluorinated monolithic stationary phase for CEC was first synthesized by a single-stage, thermally initiated copolymerization of a fluorinated monomer, 2,2,2-trifluoroethyl methacrylate (TFEM) and ethylene dimethacrylate (EDMA) in the presence of a porogen mixture. In this preparation, 2-acrylamido-2-methyl-1-propanesulfonic acid
Grafting modification of ramie fibers with poly (2, 2, 2-trifluoroethyl methacrylate) via reversible addition-fragmentation chain transfer (RAFT) polymerization in supercritical carbon dioxide
Liu X, et al.
Reactive and Functional Polymers, 70(12), 972-979 (2010)
Preparation and surface properties of poly (2, 2, 2-trifluoroethyl methacrylate) coatings modified with methyl acrylate
Xu A, et al.
Journal of Coatings Technology and Research, 13(5), 795-804 (2016)
Yoshinori Kadoma et al.
Dental materials journal, 28(5), 642-648 (2009-10-14)
In order to clarify the effect of fluorination of an adhesive resin on the durability of the resin bond to precious metal alloys, 2,2,2-trifluoroethyl methacrylate (TFEMA)-poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA)/TBBO adhesive resin was prepared. The tensile bond strength of this resin to

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