369330

N-tert-Butyltrimethylsilylamin

98%

• Synonym(e): N-(Trimethylsilyl)-tert.-butylamin
• Lineare Formel: (CH₃)₃SiNHC(CH₃)₃
• CAS-Nummer: 5577-67-3
• Molekulargewicht: 145.32
• Beilstein: 1734528
• MDL-Nummer: MFCD00054891
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24862959
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.406 (lit.)
• bp: 118-119 °C (lit.)
• Dichte: 0.762 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine
• SMILES String: CC(C)(C)N[Si](C)(C)C
• InChI: 1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
• InChIKey: GVHIREZHTRULPT-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

N-tert-Butyltrimethylsilylamine (Me₃SiNH-t-Bu) reacts with [Cp*Rh(H₂O)₃](OTf)₂ in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh₃(μ-OH)3(μ₃-OH)](OTf)₃(t-BuNH₃).

Anwendung

Applications include the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05
• Signalwort: Danger
• H-Sätze: H226,H314
• P-Sätze: P280 - P305 + P351 + P338 - P310
• Gefahreneinstufungen: Flam. Liq. 3 - Skin Corr. 1B
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 78.8 °F - closed cup
• Flammpunkt (°C): 26 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter