338370

Pentamethylcyclopentadienylrhodium(III)-chlorid-Dimer

97%

• Synonym(e): 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
• Lineare Formel: [Rh(C₅Me₅)Cl₂]₂
• CAS-Nummer: 12354-85-7
• Molekulargewicht: 618.08
• MDL-Nummer: MFCD00061552
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24860540
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• Eignung der Reaktion: core: rhodium; reaction type: C-H Activation; reagent type: catalyst; reaction type: C-Mannosylation
• SMILES String: Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChI: 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• InChIKey: QNIVKTTWBMFSBR-UHFFFAOYSA-J

Beschreibung

Anwendung

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for:

• Oxidative olefination reactions
• C-C bond cleavage of secondary alcohols
• Ortho C-H olefination of phenol derivatives
• Oxidative annulation of pyridines
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond
• Amidation reactions
• Reductive alkylation reactions

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:

• Oxidative olefination reactions
• C-C bond cleavage of secondary alcohols
• Ortho C-H olefination of phenol derivatives
• Oxidative annulation of pyridines
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond
• Amidation reactions
• Reductive alkylation reactions

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302 + H312 + H332,H315
• P-Sätze: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves