247820
1,2,3,4-Tetrahydro-1-naphthylamin
97%
Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
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About This Item
Empirische Formel (Hill-System):
C10H13N
CAS-Nummer:
Molekulargewicht:
147.22
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
97%
Form
liquid
Brechungsindex
n20/D 1.562 (lit.)
bp
246-247 °C/714 mmHg (lit.)
Dichte
1.026 g/mL at 25 °C (lit.)
SMILES String
NC1CCCc2ccccc12
InChI
1S/C10H13N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7,11H2
InChIKey
JRZGPXSSNPTNMA-UHFFFAOYSA-N
Allgemeine Beschreibung
(R)-1,2,3,4-Tetrahydro-1-naphthylamine is an efficient reagent for iodocyclization of 4-aryl-4-pentenoic acids.
Anwendung
1,2,3,4-Tetrahydro-1-naphthylamine has been used in the preparation of new chiral phosphine-aminophosphine ligands.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
235.4 °F - closed cup
Flammpunkt (°C)
113 °C - closed cup
Persönliche Schutzausrüstung
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Modular Phosphine-Aminophosphine Ligands Based on Chiral 1, 2, 3, 4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations.
Qiu M, et al.
Advanced Synthesis & Catalysis, 350(17), 2683-2689 (2008)
Jürgen Haas et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(19), 5777-5785 (2005-07-23)
Lactonizations are important steps in many synthetic sequences. Substrate-controlled reactions that use chiral auxiliaries or chiral alkenes have already been studied in depth. This study focuses on stereoselective reagent-controlled iodolactonizations, by application of a new method that uses complexes of
J S Shin et al.
Biotechnology and bioengineering, 73(3), 179-187 (2001-03-21)
A kinetic resolution process for the production of chiral amines was developed using an enzyme-membrane reactor (EMR) and a hollow-fiber membrane contactor with (S)-specific omega-transaminases (omega-TA) from Vibrio fluvialis JS17 and Bacillus thuringiensis JS64. The substrate solution containing racemic amine
Noelia Madroñal et al.
Nature communications, 7, 10923-10923 (2016-03-19)
The hippocampus is critical for the acquisition and retrieval of episodic and contextual memories. Lesions of the dentate gyrus, a principal input of the hippocampus, block memory acquisition, but it remains unclear whether this region also plays a role in
Effects of isomers of apomorphines on dopamine receptors in striatal and limbic tissue of rat brain.
N S Kula et al.
Life sciences, 37(11), 1051-1057 (1985-09-16)
The optical isomers of apomorphine (APO) and N-propylnorapomorphine (NPA) were interacted with three biochemical indices of dopamine (DA) receptors in extrapyramidal and limbic preparations of rat brain tissue. There were consistent isomeric preferences for the R(-) configuration of both DA
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