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148229

Thiobenzamid

Name: Thiobenzamid
Brand: ALDRICH

98%

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About This Item

Lineare Formel:

C₆H₅CSNH₂

CAS-Nummer:

2227-79-4

Molekulargewicht:

137.20

Beilstein:

606021

EG-Nummer:

218-765-6

MDL-Nummer:

MFCD00008060

UNSPSC-Code:

12352100

PubChem Substanz-ID:

24848890

NACRES:

NA.22

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Slide 1 of 1

1 of 1

Sigma-Aldrich

C0267

2-Chloracetamid

Assay

98%

mp (Schmelzpunkt)

113-117 °C (lit.)

Funktionelle Gruppe

amine
phenyl

SMILES String

NC(=S)c1ccccc1

InChI

1S/C7H7NS/c8-7(9)6-4-2-1-3-5-6/h1-5H,(H2,8,9)

InChIKey

QIOZLISABUUKJY-UHFFFAOYSA-N

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Anwendung

Thiobenzamide was used to prepare amide and amidine adducts. It was also used in the synthesis of 4-oxo-4H-chromene-3-carbothioic acid N-phenylamides.

Piktogramme

GHS06

Signalwort

Danger

H-Sätze

H301

P-Sätze

P264 - P270 - P301 + P310 - P405 - P501

Gefahreneinstufungen

Acute Tox. 3 Oral

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Slide 1 of 1

1 of 1

Sigma-Aldrich

172502

Thioacetamid

Protein targets of thioacetamide metabolites in rat hepatocytes.

Yakov M Koen et al.

Chemical research in toxicology, 26(4), 564-574 (2013-03-08)

Thioacetamide (TA) has long been known as a hepatotoxicant whose bioactivation requires S-oxidation to thioacetamide S-oxide (TASO) and then to the very reactive S,S-dioxide (TASO2). The latter can tautomerize to form acylating species capable of covalently modifying cellular nucleophiles including

Persistent chemopreventive effect of S-adenosyl-L-methionine on the development of liver putative preneoplastic lesions induced by thiobenzamide in diethylnitrosamine-initiated rats.

M M Simile et al.

Carcinogenesis, 17(7), 1533-1537 (1996-07-01)

S-Adenosyl-L-methionine (SAM) is a strong chemopreventive agent of rat liver carcinogenesis. Examination was made to determine whether inhibition by SAM of the development of preneoplastic liver lesions persists to SAM withdrawal in diethylnitrosamine-initiated F344 rats promoted with thiobenzamide (TB). The

Induction of flavin-containing monooxygenase (FMO1) by a polycyclic aromatic hydrocarbon, 3-methylcholanthrene, in rat liver.

W G Chung et al.

Molecules and cells, 7(6), 738-741 (1998-03-24)

Flavin-containing monooxygenase (FMO), known not to be induced by xenobiotics, has been induced by a polycyclic aromatic hydrocarbon, 3-methylcholanthrene (3MC). We have found a prominent augmentation of hepatic FMO1 both at transcription and translation levels by pretreatment of rats with

Presence of flavin-containing monooxygenase in rat brain.

S Bhamre et al.

Biochemical pharmacology, 42(2), 442-444 (1991-07-05)

Relative hepatotoxicity of 2-(substituted phenyl)thiazoles and substituted thiobenzamides in mice: evidence for the involvement of thiobenzamides as ring cleavage metabolites in the hepatotoxicity of 2-phenylthiazoles.

T Mizutani et al.

Toxicology letters, 85(2), 101-105 (1996-05-01)

The hepatotoxicity of the 3 isomers of para-substituted thiobenzamides and the 3 isomers of 2-(para-substituted phenyl)-4-methylthiazoles was evaluated in mice depleted of glutathione (GSH) by pretreatment with buthionine sulfoximine (BSO). In accordance with previous studies with the rat, p-methoxythiobenzamide was

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