205281

Lithium perchlorate

ACS reagent, ≥95.0%

• Fórmula lineal: LiClO₄
• Número de CAS: 7791-03-9
• Peso molecular: 106.39
• EC Number: 232-237-2
• MDL number: MFCD00011079
• UNSPSC Code: 12352302
• PubChem Substance ID: 329752010
• NACRES: NA.21
• assay: ≥95.0%
• grade: ACS reagent
• form: powder, chunks or granules

Propiedades

• grade: ACS reagent
• Quality Level: 200
• assay: ≥95.0%
• form: powder, chunks or granules
• reaction suitability: reagent type: oxidant
• impurities: ≤0.005% insolubles
• pH: 6.0-7.5 (25 °C, 5%)
• mp: 236 °C (lit.)
• anion traces: chloride (Cl^-): ≤0.003%; sulfate (SO₄^2-): ≤0.001%
• cation traces: Fe: ≤5 ppm; heavy metals: ≤5 ppm (by ICP-OES)
• SMILES string: [Li+].[O-]Cl(=O)(=O)=O
• InChI: 1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI key: MHCFAGZWMAWTNR-UHFFFAOYSA-M

Descripción

General description

Lithium perchlorate (LiClO₄) is a colorless lithium salt. On the crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO₄.3H₂O). It can be synthesized by reacting lithium chloride with perchloric acid.

Application

Lithium perchlorate (LiClO₄) may be used as a catalyst in the synthesis of bis(indolyl)methanes.

Lithium perchlorate may be used to catalyze:

• The acylation of hindered alcohols and phenols under solvent-free conditions.
• 1,4-Conjugate addition of O-silylated ketene acetals to hindered αβ,-unsaturated carbonyl system.
• The protection of amine groups as N-Boc derivatives via tert-butoxycarbonylation.
• Synthesis of α-aminophosphonates under solvent free conditions.

When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.

Información de seguridad

• pictograms: GHS03,GHS05,GHS07
• signalword: Danger
• hcodes: H272,H302,H314,H335
• pcodes: P210 - P260 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1A - Strongly oxidizing hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable