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P50919

Sigma-Aldrich

Propargylamine hydrochloride

95%

Sinónimos:

2-Propynylamine hydrochloride, 3-Amino-1-propyne hydrochloride

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About This Item

Fórmula lineal:
HC≡CCH2NH2 · HCl
Número de CAS:
15430-52-1
Peso molecular:
91.54
Beilstein/REAXYS Number:
3669858
EC Number:
239-440-5
MDL number:
MFCD00012907
UNSPSC Code:
12352100
PubChem Substance ID:
24898593
NACRES:
NA.22

assay

95%

form

powder

reaction suitability

reaction type: click chemistry

mp

179-182 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl.NCC#C

InChI

1S/C3H5N.ClH/c1-2-3-4;/h1H,3-4H2;1H

InChI key

IKXNIQJDNKPPCH-UHFFFAOYSA-N

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pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Olga P Pereshivko et al.
Organic letters, 12(11), 2638-2641 (2010-05-06)
An efficient, microwave-assisted Cu(I)-catalyzed one-pot coupling of a ketone, an alkyne, and a primary amine (KA(2) coupling) is described, giving access to secondary propargylamines.
Parminder Kaur et al.
Organic & biomolecular chemistry, 8(5), 1091-1096 (2010-02-19)
A variety of substituted chiral propargylamines have been synthesized by reacting chiral N-phosphonylimines with lithium aryl/alkyl acetylides. Seventeen examples were studied to give excellent yields (>90%) and diastereoselectivities (96 : 4 to 99 : 1). It was found that the
The marriage of organocatalysis with metal catalysis: access to multisubstituted chiral 2,5-dihydropyrroles by cascade iminium/enamine-metal cooperative catalysis.
Wangsheng Sun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(50), 13958-13962 (2011-11-19)
Claudio Gnaccarini et al.
Organic & biomolecular chemistry, 10(27), 5258-5265 (2012-06-02)
Transglutaminases (TGases) catalyse the transamidation of glutamine residues with primary amines. Herein we report the first FRET-based activity assay for the direct detection of the ligation (transamidation) reaction mediated by tissue TGase (TG2). This novel assay was then used in
Adrian Sulistio et al.
Chemical communications (Cambridge, England), 47(4), 1151-1153 (2010-12-15)
Highly functionalized water soluble core cross-linked star (CCS) polymers having degradable cores and hierarchical functionalities spanning from the peripheral groups along the arms to the core have been synthesized entirely from amino acid building blocks. The core-isolated moieties were shown
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