928305

cataCXium^® A Pd G3 ChemBeads

• Sinónimos: Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
• Fórmula empírica (notación de Hill): C₃₇H₅₂NO₃PPdS
• Número de CAS: 1651823-59-4
• Peso molecular: 728.27
• MDL number: MFCD28144563
• UNSPSC Code: 12352101
• NACRES: NA.82

Propiedades

• form: solid
• Quality Level: 100
• composition: ~ 4 wt.% loading of catalyst
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• SMILES string: [Pd+2].P(C76CC8CC(C7)CC(C6)C8)(C43CC5CC(C4)CC(C3)C5)CCCC.[S](=O)(=O)([O-])C.Nc1c(cccc1)c2[c-]cccc2
• InChI key: QFHMWCPYABRFMY-UHFFFAOYSA-M

Descripción

Application

cataCXium^® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

• Direct ortho-arylation of pyridinecarboxylic acids.
• Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
• Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
• Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG

Información de seguridad

• pictograms: GHS08
• signalword: Danger
• hcodes: H350i
• pcodes: P201 - P202 - P280 - P308 + P313 - P405 - P501
• Hazard Classifications: Carc. 1B Inhalation
• Storage Class: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• wgk_germany: WGK 3