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Merck

255645

Sigma-Aldrich

Carbonato de cesio

99.995% trace metals basis

Sinónimos:

Ácido carbónico dicesio

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About This Item

Fórmula lineal:
Cs2CO3
Número de CAS:
Peso molecular:
325.82
Beilstein/REAXYS Number:
4546405
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.995% trace metals basis

form

powder

mp

610 °C (dec.) (lit.)

application(s)

battery manufacturing

SMILES string

[Cs+].[Cs+].[O-]C([O-])=O

InChI

1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

FJDQFPXHSGXQBY-UHFFFAOYSA-L

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General description

Cesium carbonate is a mild inorganic base widely used inelectroluminescent devices and organic synthesis. Due to its excellent electroninjection capability, it is used as an interface modifying material in organiclight-emitting diodes (OLED), organic field effect transistors (OFET), organicsolar cells (OSCs), and perovskite solar cells.

Application

Cesium carbonate can be used as:
  • A cathode buffer layer to enhance device stability and power conversion efficiency in polymer solar cells.
  • A precursor to prepare alkali-based electrolyte for selective reduction of CO2 by electrocatalysis.
  • A base in many organic transformations such as C, N, O alkylation, and arylation reactions.
Promueve la O-alquilación eficiente de los alcoholes para formar carbonatos de alquilo mixtos.

pictograms

Health hazardCorrosion

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral

target_organs

Kidney,Adrenal gland,Testes

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Journal of materials chemistry. C, 6(37), 10101-10105 (2018-12-07)
Lead halide perovskite nanocrystals (NCs) exhibit excellent tunable emissions covering the entire visible spectral region, but they do not emit near-infrared (NIR) light. We synthesized rare earth element doped CsPbCl3 NCs for NIR emission. The Yb3+ doped CsPbCl3 NCs emitted
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Tetrahedron Letters, 40, 1847-1847 (1999)
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Nature, 531(7593), 215-219 (2016-03-11)
Using carbon dioxide (CO2) as a feedstock for commodity synthesis is an attractive means of reducing greenhouse gas emissions and a possible stepping-stone towards renewable synthetic fuels. A major impediment to synthesizing compounds from CO2 is the difficulty of forming
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Semiconductor nanorods (NRs) offer the useful property of linearly polarized light emission. While this would be an attractive functionality for strongly emitting perovskite nanoparticles, to date, there has been limited success in demonstrating a direct chemical synthesis of cesium lead

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