244260

Hydrobromic acid

ACS reagent, 48%

• Empirical Formula (Hill Notation): HBr
• CAS Number: 10035-10-6
• Molecular Weight: 80.91
• Beilstein: 3587158
• MDL number: MFCD00011323
• UNSPSC Code: 12352106
• PubChem Substance ID: 329752491
• NACRES: NA.21

Properties

• grade: ACS reagent
• Quality Level: 200
• vapor density: 2.8 (vs air)
• vapor pressure: 320 psi ( 21.1 °C); 8 mmHg ( 25 °C)
• description: 48% aqueous HBr
• Assay: 47.0-49.0% (ACS specification); 48%
• form: liquid
• ign. residue: ≤0.002%
• density: 1.49 g/mL at 25 °C (lit.)
• anion traces: SO₄^2- and SO₃^2-: ≤0.003%; chloride (Cl^-): ≤0.05%; iodide (I^-): ≤0.003%; phosphate (PO₄^3-): ≤0.001%
• cation traces: Fe: ≤1 ppm; Se: ≤0.01 ppm; heavy metals: ≤5 ppm (by ICP-OES)
• SMILES string: Br
• InChI: 1S/BrH/h1H
• InChI key: CPELXLSAUQHCOX-UHFFFAOYSA-N

Description

General description

Hydrobromic acid is a strong acid that can be used as a brominating reagent for the electrophilic and radical bromination of olefins, alkynes, and ketones.

Application

Hydrobromic acid can be used as a brominating agent:

• For the regioselective bromination of anilides to bromoanilides.
• Oxidative bromination of olefins, alkynes, and ketones to corresponding dibrominated alkanes, dibrominated alkenes, and α-bromoketones.

It can also be used as a catalyst for the aerobic photooxidation of alcohols to corresponding carboxylic acids.

Other Notes

ACS specifications same as product 438065

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H290,H314,H335
• Precautionary Statements: P234 - P261 - P271 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable