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76040

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Palladium Matrix Modifier

for graphite furnace-AAS

Synonym(s):

Palladium(II) nitrate – nitric acid solution, Palladium modifier

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12000000
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.21

grade

for graphite furnace-AAS

Quality Level

form

liquid

mol wt

Mr 230.41 g/mol

reaction suitability

reagent type: catalyst
core: palladium

concentration

10.0 g/L±0.3 g/L Pd

cation traces

Ag: ≤0.1 mg/kg
As: ≤0.01 mg/kg
Cd: ≤0.001 mg/kg
Pb: ≤0.01 mg/kg
Se: ≤0.1 mg/kg
Tl: ≤0.02 mg/kg

SMILES string

[Pd].O[N+]([O-])=O

InChI

1S/HNO3.Pd/c2-1(3)4;/h(H,2,3,4);

InChI key

UVCRDXRRYBAMHB-UHFFFAOYSA-N

General description

Matrix modifier in general, is a buffer that is similar to the chemical environment of aqueous standards and samples. It can also make analyte more thermally stable salts, oxides or metal compounds. It also reduces the volatility of analyte.

Application

Palladium matrix modifier may be used in determination of total arsenic by in situ oxidation of diluted urine using graphite furnace atomic absorption spectrophotometer.

Components

Pd(NO3)2.2H2O in 13-20% nitric acid

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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D E Nixon et al.
Clinical chemistry, 37(9), 1575-1579 (1991-09-01)
We evaluated the effectiveness of nickel and palladium with or without added potassium persulfate as matrix modifiers for the determination of total arsenic in urine. Complete recovery of pure aqueous solutions of As(III), As(V), cacodylic acid (DMA), monomethylarsinic acid (MMA)
Lauri H. J. Lajunen, P. Peramaki
Spectrochemical Analysis by Atomic Absorption and Emission, 143 -143 (2004)

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