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44920

Sigma-Aldrich

Iron(III) acetylacetonate

purum, ≥97.0% (RT)

Synonym(s):

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Linear Formula:
Fe(C5H7O2)3
CAS Number:
14024-18-1
Molecular Weight:
353.17
Beilstein:
4157960
EC Number:
237-853-5
MDL number:
MFCD00000020
UNSPSC Code:
12352300
PubChem Substance ID:
329756564
NACRES:
NA.23

grade

purum

Quality Level

200

Assay

≥97.0% (RT)

form

powder

reaction suitability

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)
180-190 °C (dec.)

density

5.24 g/mL at 25 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

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Related Categories

Application

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Other Notes

Catalyst used in Grignard reactions with acid chlorides to give ketones

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332 - H318

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB3470
BCBV4183
BCBT5666
BCBS5090V
BCBR4648V

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V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere.
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