P66203
trans-3-(3-Pyridyl)acrylic acid
99%
Synonym(s):
3-Pyridineacrylic acid
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About This Item
Empirical Formula (Hill Notation):
C8H7NO2
CAS Number:
Molecular Weight:
149.15
Beilstein:
113290
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
form
solid
mp
232-235 °C (dec.) (lit.)
SMILES string
[H]\C(=C(\[H])c1cccnc1)C(O)=O
InChI
1S/C8H7NO2/c10-8(11)4-3-7-2-1-5-9-6-7/h1-6H,(H,10,11)/b4-3+
InChI key
VUVORVXMOLQFMO-ONEGZZNKSA-N
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General description
trans-3-(3-Pyridyl)acrylic acid, a bifunctional ligand with both hard and soft coordination sites, is mainly used in constructing heterometallic complexes.
Application
trans-3-(3-Pyridyl)acrylic acid has been used as an organic linker to connect d and f block metals to form a 3D heterometallic coordination polymer with luminescence property. It may also be used in the synthesis of ethyl trans-3-(3-pyridyl)acrylate via esterification.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Matrix?assisted laser desorption mass spectrometry of homopolymer oligodeoxyribonucleotides. Influence of base composition on the mass spectrometric response.
Schneider K
Journal of Mass Spectrometry : Jms, 28(11), 1353-1361 (1993)
A highly stereoselective Michael addition to an. alpha.,. beta.-unsaturated ester as the crucial step in the synthesis of a novel. beta.-amino acid-containing fibrinogen receptor antagonist.
Rico J
The Journal of Organic Chemistry, 58(27), 7948-7951 (1993)
Uranyl Ion Complexes with trans?3?(3?Pyridyl) acrylic Acid Including a Uranyl?Copper (II) Heterometallic Framework.
Thuery P
European Journal of Inorganic Chemistry, 2014(28), 4772-4778 (2014)
Novel coordination polymers and structural systematics in the hydrothermal M, M? trans-3 (-3-pyridyl) acrylic acid system.
Gunning N
Dalton Transactions, 16, 2788-2792 (2005)
Assembling metals (Co II and Mn II) with pyridylcarboxylates in the presence of azide: synthesis, structural aspects and magnetic behavior of three coordination polymers.
Mondal K
Dalton Transactions, 6, 767-775 (2008)
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