ALD00612
(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide
≥95%
Synonym(s):
Yu MPAAM ligand
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About This Item
Empirical Formula (Hill Notation):
C13H20N2O
CAS Number:
Molecular Weight:
220.31
UNSPSC Code:
12352200
NACRES:
NA.22
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Assay
≥95%
form
powder
reaction suitability
reaction type: C-C Bond Formation
storage temp.
−20°C
Related Categories
Application
(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide is an MPAAM ligand developed in the Yu Group for the Pd-catalyzed enantioselective C(sp3)-H arylation of fre cyclopropanecarboxylic and aminoisobutyric acids.
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Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Peng-Xiang Shen et al.
Journal of the American Chemical Society, 140(21), 6545-6549 (2018-05-10)
A monoprotected aminoethyl amine chiral ligand based on an ethylenediamine backbone was developed to achieve Pd-catalyzed enantioselective C(sp3)-H arylation of cyclopropanecarboxylic and 2-aminoisobutyric acids without using exogenous directing groups. This new chiral catalyst affords new disconnection for preparing diverse chiral
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