932663

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline

≥99% (HPLC)

• Synonym(s): Bathocuproine, 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
• Empirical Formula (Hill Notation): C₂₆H₂₀N₂
• CAS Number: 4733-39-5
• Molecular Weight: 360.45
• Beilstein: 306714
• MDL number: MFCD00004972
• UNSPSC Code: 41106305
• NACRES: NA.23

Properties

• grade: sublimed grade
• Quality Level: 100
• description: µe ≈ 5.5 x 10^-6 cm²V^-1s^-1
• Assay: ≥99% (HPLC)
• loss: 0.5% TGA, >240°C (weight loss)
• mp: 279-283 °C (lit.)
• solubility: chloroform: soluble; toluene: soluble
• λmax: 277 nm
• fluorescence: λ_em 386 nm±10 nm in THF
• Orbital energy: HOMO 6.4 eV ; LUMO 2.9 eV
• SMILES string: Cc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5
• InChI: 1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3
• InChI key: STTGYIUESPWXOW-UHFFFAOYSA-N

Description

Application

Use as Electron Transport / Hole Blocking Layer (ETL / HBL) in OLED and perovskite solar cells.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302,H413
• Precautionary Statements: P264 - P270 - P273 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 4
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable