Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

928917

Sigma-Aldrich

[CF3]8-DPPF

≥95%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C42H20F24FeP2
CAS Number:
70236-68-9
Molecular Weight:
1098.36
NACRES:
NA.21

Quality Level

100

Assay

≥95%

form

powder

reaction suitability

reagent type: ligand

mp

154-155 °C

functional group

phosphine

SMILES string

C[Fe]C.FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)c3cccc3)=C1)(F)F.FC(C4=CC(C(F)(F)F)=CC(P(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)c6cccc6)=C4)(F)F

Application

[CF3]8-DPPF is a ferrocenyl phosphine ligand used in a mild Ni catalyzed C-N cross coupling reaction.

Other Notes

The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Sorry, we don't have COAs for this product available online at this time.

If you need assistance, please contact Customer Support.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Richard Y Liu et al.
Journal of the American Chemical Society, 142(9), 4500-4507 (2020-02-11)
Palladium-catalyzed amination reactions using soluble organic bases have provided a solution to the many issues associated with heterogeneous reaction conditions. Still, homogeneous C-N cross-coupling approaches cannot yet employ bases as weak and economical as trialkylamines. Furthermore, organic base-mediated methods have

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service