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913529

Sigma-Aldrich

Birch O-PC C0102

≥97%, New Iridium

Synonym(s):

2-(2-Ethylhexyl)-6,8,11-triphenyl-1H-peryleno[1,12-efg]isoindole-1,3(2H)-dione, BPI-Ph

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About This Item

Empirical Formula (Hill Notation):
C50H39NO2
Molecular Weight:
685.85
UNSPSC Code:
12352200

Assay

≥97%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

Application

Birch O-PC C0102 is an organic photocatalyst developed in the Miyake lab for the photocatalytic Birch reduction driven by visible light. The hallmark high excited state redox potential of this first of its kind catalyst class reduces benzene and other arenes to produce functionally useful 1,4-cyclohexadienes. This organic photocatalyst accesses both classical and non-classical Birch reduction reactivity in addition to demonstrating hydrodechlorination of aromatics. Employing mild benchtop conditions, this photocatalytic approach eliminates challenges associated with traditional Birch reduction such as the use of alkali metals in liquid ammonia.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Legal Information

Sold in collaboration with New Iridium LLC. For orders greater than 25g, please contact New Iridium at chern@newiridium.com or visit https://www.newiridium.com.
Birch O-PC is a trademark of New Iridium Inc.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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