910228
1,3,5,7-Tetramethyl-2,4,8-trioxo-6-(2-bromophenyl)-6-phosphaadamantane
≥95%
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About This Item
Empirical Formula (Hill Notation):
C16H20BrO3P
CAS Number:
Molecular Weight:
371.21
UNSPSC Code:
12352200
Recommended Products
![[(1,3,5,7-Tetramethyl-6-phenyl-2,4,6-trioxa-6-phosphaadamantane)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate](/deepweb/assets/sigmaaldrich/product/structures/324/001/3ffb4bd2-9c6b-451c-80ee-a217f03ca932/640/3ffb4bd2-9c6b-451c-80ee-a217f03ca932.png)
Assay
≥95%
form
powder or crystals
reaction suitability
reagent type: ligand
mp
151 °C
functional group
phosphine
Application
1,3,5,7-Tetramethyl-2,4,8-trioxo-6-(2-bromophenyl)-6-phosphaadamantane is a precursor to PAd-Dalphos (900593) and related phosphine ligands developed by the Stradiotto lab.
related product
Product No.
Description
Pricing
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Christopher M Lavoie et al.
Nature communications, 7, 11073-11073 (2016-03-24)
Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical industry, for the synthesis of (hetero)aniline derivatives. However, the cost and relative scarcity of palladium provides motivation for the development of alternative, more
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