772976
Di(1-adamantyl)-(2-triisopropylsiloxyphenyl)phosphine
97%
Synonym(s):
OTIPS-DalPhos
About This Item
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Assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
218-223 °C
functional group
phosphine
SMILES string
CC(C)[Si](Oc1ccccc1P([C@]23C[C@H]4C[C@H](C[C@H](C4)C2)C3)[C@]56C[C@H]7C[C@H](C[C@H](C7)C5)C6)(C(C)C)C(C)C
InChI
1S/C35H55OPSi/c1-23(2)38(24(3)4,25(5)6)36-32-9-7-8-10-33(32)37(34-17-26-11-27(18-34)13-28(12-26)19-34)35-20-29-14-30(21-35)16-31(15-29)22-35/h7-10,23-31H,11-22H2,1-6H3/t26-,27+,28-,29-,30+,31-,34-,35-
InChI key
LAQRMRNBWOVSBV-QDACEEAESA-N
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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The main focus of the Stradiotto group has centered on the development and application of novel electronically rich, sterically encumbered P,N-based ancillary ligands for use in late metal catalysis, including Pd and Au chemistry.
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