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698539

Sigma-Aldrich

Bis(p-sulfonatophenyl)phenylphosphine dihydrate dipotassium salt

97%

Synonym(s):

BSPP, 4,4′-(Phenylphosphinidene)bis-benzenesulfonic acid dipotassium salt

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About This Item

Empirical Formula (Hill Notation):
C18H13K2O6PS2 · 2H2O
CAS Number:
Molecular Weight:
534.62
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

solid

reaction suitability

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

98-102 °C

functional group

phosphine

SMILES string

O.O.[K+].[K+].[O-]S(=O)(=O)c1ccc(cc1)P(c2ccccc2)c3ccc(cc3)S([O-])(=O)=O

InChI

1S/C18H15O6PS2.2K.2H2O/c19-26(20,21)17-10-6-15(7-11-17)25(14-4-2-1-3-5-14)16-8-12-18(13-9-16)27(22,23)24;;;;/h1-13H,(H,19,20,21)(H,22,23,24);;;2*1H2/q;2*+1;;/p-2

InChI key

CVKCKLNGVYHFAX-UHFFFAOYSA-L

Application

Bis(p-sulfonatophenyl)phenylphosphine dihydrate dipotassium salt (BSPP) is a water-soluble triarylphosphine salt that forms coordination complexes with silver ions, which is extensively used in the synthesis of silver nanoparticles (AgNPs).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Photomediated synthesis of silver triangular bipyramids and prisms: the effect of pH and BSPP.
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Chirality of self-assembled metal-semiconductor nanostructures.
Sun, Maozhong et al.
Journal of Material Chemistry C, 2(15), 2702-2706 (2014)
Mechanistic study of photomediated triangular silver nanoprism growth.
Xue, Can et al.
Journal of the American Chemical Society, 130(26), 8337-8344 (2008)

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