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675601

Sigma-Aldrich

1,1′-Bis[(2R,5R)-2,5-dimethylphospholano]ferrocene

≥97%

Synonym(s):

R,R-Me-Ferrocelane™

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About This Item

Empirical Formula (Hill Notation):
C22H32FeP2
CAS Number:
540475-45-4
Molecular Weight:
414.28
UNSPSC Code:
12352005
PubChem Substance ID:
24885292
NACRES:
NA.22

Quality Level

100

Assay

≥97%

form

solid

mp

99.9-101.5 °C

SMILES string

C[Fe]C.C[C@@H]1CC[C@@H](C)P1[C@H]2CCCC2.C[C@@H]3CC[C@@H](C)P3[C@@H]4CCCC4

InChI

1S/2C11H21P.2CH3.Fe/c2*1-9-7-8-10(2)12(9)11-5-3-4-6-11;;;/h2*9-11H,3-8H2,1-2H3;2*1H3;/t2*9-,10-;;;/m11.../s1

InChI key

TZPGMNOFYCAGIA-UIBZXYQVSA-N

Related Categories

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Legal Information

Sold in collaboration with Kanata Chemical Technoligies, Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
06004KE
01125JE

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Sigma-Aldrich

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Articles

DuPhos and BPE Ligands

Asymmetric hydrogenation reactions represent the ideal process for the commercial manufacture of single-enantiomer compounds, because of the ease by which these robust procedures can be scaled up and because of the low levels of byproducts generated in these asymmetric hydrogenations.

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