673307

Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate

• Synonym(s): (Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate, Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
• Linear Formula: [(C₅H₅)Ru(CH₃CN)₃]PF₆
• CAS Number: 80049-61-2
• Molecular Weight: 434.28
• MDL number: MFCD02684569
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760546
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: core: ruthenium; reagent type: catalyst
• storage temp.: 2-8°C
• SMILES string: [Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
• InChI: 1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
• InChI key: HJQVFVSAQOQXRG-UHFFFAOYSA-N

Description

Application

Catalyst for:

• Regioselective and stereoselective dehydrative allylation of nucleophiles
• O-H Insertion and condensation reactions
• Hydrosilylation
• Decarboxylative allylic etherification
• Claisen rearrangement of unactivated allyl vinyl ethers

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves