64296
(Trimethylsilyl)methanesulfonate
≥97%
Synonym(s):
Methanesulfonic acid trimethylsilyl ester, Trimethylsilyl mesylate
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About This Item
Linear Formula:
H3CSO3OSi(CH3)3
CAS Number:
Molecular Weight:
168.29
Beilstein:
2076698
EC Number:
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥97%
form
liquid
refractive index
n20/D 1.422 (lit.)
n20/D 1.422
bp
103-104 °C/25 mmHg (lit.)
density
1.09 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)OS(C)(=O)=O
InChI
1S/C4H12O3SSi/c1-8(5,6)7-9(2,3)4/h1-4H3
InChI key
BCHASIUOFGDRIO-UHFFFAOYSA-N
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Application
Reactant or reagent involved in:
- Reduction of esters to ethers using boron difluoride triflate etherate
- Elimination of C(8)-functional groups via regioselective dehydration
- Dealkylsilylation of alumazene derivatives
Other Notes
Silylating agent
Signal Word
Warning
Hazard Statements
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
86.0 °F - closed cup
Flash Point(C)
30 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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J G Jun et al.
Carbohydrate research, 163(2), 247-261 (1987-06-15)
Several per-O-methylated D-glucans and D-fructans were used as models in an attempt to identify new catalysts for carrying out reductive cleavage. Included in these model studies were several D-glucans that contained 4-linked D-glucopyranosyl residues as well as one having a
H.H. Hergott et al.
Liebigs Ann. Chem., 1718-1718 (1980)
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