559873

Dess-Martin periodinane solution

0.3 M in methylene chloride

• Synonym(s): 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one, Dess-Martin reagent, Triacetoxyperiodinane
• CAS Number: 87413-09-0
• MDL number: MFCD00130127
• UNSPSC Code: 12352005
• PubChem Substance ID: 24879825
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: reagent type: oxidant
• concentration: 0.3 M in methylene chloride
• bp: 40 °C
• density: 1.369 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
• InChI: 1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
• InChI key: NKLCNNUWBJBICK-UHFFFAOYSA-N

Description

Application

Widely used reagent for the mild oxidation of alcohols to aldehydes and ketones.

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H336,H351
• Precautionary Statements: P202 - P261 - P264 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Central nervous system
• Supplementary Hazards: EUH044
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves