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557684

Sigma-Aldrich

5-Bromo-2-thienylboronic acid

≥95%

Synonym(s):

5-Bromothiophene-2-boronic acid

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About This Item

Empirical Formula (Hill Notation):
C4H4BBrO2S
CAS Number:
162607-17-2
Molecular Weight:
206.85
MDL number:
MFCD02094028
UNSPSC Code:
12352103
PubChem Substance ID:
24879688
NACRES:
NA.22

Quality Level

100

Assay

≥95%

form

solid

mp

95-100 °C (lit.)

storage temp.

2-8°C

SMILES string

OB(O)c1ccc(Br)s1

InChI

1S/C4H4BBrO2S/c6-4-2-1-3(9-4)5(7)8/h1-2,7-8H

InChI key

USJPOBDLWVCPGG-UHFFFAOYSA-N

Related Categories

Application

Reactant involved in:
  • Suzuki coupling reactions for the synthesis of benzotriazole-containing organic sensitizers and meso-Polyarylamide-BODIPY hybrids
  • Suzuki-Miyaura coupling for the synthesis of ratanhine
  • Microwave-assisted Sonogashira reactions for the synthesis of ethynylarylboronates

Other Notes

Contains varying amounts of anhydride

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBH9519
MKBZ8518V
SHBD5878V
MKBN9807V
81796DJV

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Yu Otsuka et al.
Materials (Basel, Switzerland), 13(20) (2020-10-15)
We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki-Miyaura cross-coupling between 4-iodobenzoic acid immobilized on Wang

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Suzuki–Miyaura Coupling Reagents

This brochure contains a comprehensive selection of boronic acids, boronic acid esters, diboron esters, and transition-metal catalysts useful for the Suzuki–Miyaura coupling reaction

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