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499382

Sigma-Aldrich

2-Pyridylzinc bromide solution

0.5 M in THF

Synonym(s):

Bromo-2-pyridinylzinc, Pyridin-2-ylzinc bromide

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About This Item

Empirical Formula (Hill Notation):
C5H4BrNZn
CAS Number:
218777-23-2
Molecular Weight:
223.39
MDL number:
MFCD00671985
UNSPSC Code:
12352103
PubChem Substance ID:
24873276
NACRES:
NA.22

Quality Level

100

concentration

0.5 M in THF

density

0.974 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]c1ccccn1

InChI

1S/C5H4N.BrH.Zn/c1-2-4-6-5-3-1;;/h1-4H;1H;/q;;+1/p-1

InChI key

XYTLXTHDABUPLT-UHFFFAOYSA-M

Application

Used in the preparation of P,N ligands for asymmetric Ir-catalyzed reactions.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.0 °F - closed cup

Flash Point(C)

-17.2 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN5800
BCCF9700
SHBM5001
SHBM0188
SHBL7623

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New P,N ligands for asymmetric Ir-catalyzed reactions.
Tanasri Bunlaksananusorn et al.
Angewandte Chemie (International ed. in English), 42(33), 3941-3943 (2003-09-02)

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