49661
Methyl 4-pentenoate
≥95.0% (GC)
Synonym(s):
4-Pentenoic acid methyl ester, Allylacetic acid methyl ester, Methyl allylacetate
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About This Item
Empirical Formula (Hill Notation):
C6H10O2
CAS Number:
Molecular Weight:
114.14
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥95.0% (GC)
refractive index
n20/D 1.415
n20/D 1.415
functional group
allyl
SMILES string
COC(=O)CCC=C
InChI
1S/C6H10O2/c1-3-4-5-6(7)8-2/h3H,1,4-5H2,2H3
InChI key
SHCSFZHSNSGTOP-UHFFFAOYSA-N
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General description
Methyl 4-pentenoate is an unsaturated methyl ester that is prepared by the esterification of 1-pentenoic acid with methanol. It undergoes amidation with formamide via acetone-initiated photochemical reaction to form a 1:1 adduct. The metathesis of methyl 4-pentenoate with different Mo(VI)alkylidene complexes have been reported. It acts as a chain transfer agent during the polymerization of exo,exo-5,6-bis(methoxymethyl)-7-oxabicyclo[2.2.1]hept-2-ene using RuII(H20)6(tos)2 (tos =p-toluenesulfonate) as a catalyst.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
84.2 °F - closed cup
Flash Point(C)
29 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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