454486
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
Synonym(s):
(R)-(+)-Glyceraldehyde acetonide, (R)-Isopropylideneglyceraldehyde, NSC 89869
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About This Item
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optical activity
[α]22/D +53.8°, c = 2 in chloroform
Quality Level
refractive index
n20/D 1.454 (lit.)
bp
139 °C (lit.)
density
1.045 g/mL at 25 °C (lit.)
storage temp.
−20°C
SMILES string
CC1(C)OC[C@@H](O1)C=O
InChI
1S/C6H10O3/c1-6(2)8-4-5(3-7)9-6/h3,5H,4H2,1-2H3/t5-/m0/s1
InChI key
YSGPYVWACGYQDJ-YFKPBYRVSA-N
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Application
Reactant involved in organic reactions including:
- Henry condensation reactions
- Synthesis of highly functionalized chiral aziridines
- Olefination of aldehydes
- C-H oxidations
- Aldol-type condensations
- Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents
- Hosomi-Sakurai reactions
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
143.6 °F - closed cup
Flash Point(C)
62 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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