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446319

Sigma-Aldrich

Bis(acetonitrile)dichloropalladium(II)

99.99%

Synonym(s):

Palladium(II) chloride diacetonitrile complex

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About This Item

Linear Formula:
PdCl2 · (CH3CN)2
CAS Number:
14592-56-4
Molecular Weight:
259.43
EC Number:
238-637-3
MDL number:
MFCD00013122
UNSPSC Code:
12161600
PubChem Substance ID:
24868266
NACRES:
NA.22

Quality Level

100

Assay

99.99%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES string

CC#N.CC#N.Cl[Pd]Cl

InChI

1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2

InChI key

RBYGDVHOECIAFC-UHFFFAOYSA-L

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Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301 + H311 + H331

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ1902V
MKBG8416V
MKBG0039
MKBB0042
00897KJ

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Articles

Procedures for Transition-Metal-Catalyzed Cross-Coupling Reactions in Water at Room Temperature using TPGS-750-M

TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.

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